Back to 13.3 Shifting Equilibria: Le Châtelier’s Principle

13.3 Exercise 18

Avg difficulty 2.5

A solution is saturated with silver sulfate and contains excess solid silver sulfate:
Ag2SO4(s)⇌2Ag+(aq)+SO42−(aq)\text{Ag}_{2} \text{SO}_{4} \left(s\right) \rightleftharpoons 2 \text{Ag}^{+} \left(a q\right) + \text{SO}_{4} ^{2−} \left(a q\right)

A small amount of solid silver sulfate containing a radioactive isotope of silver is added to this solution. Within a few minutes, a portion of the solution phase is sampled and tests positive for radioactive Ag+ ions. Explain this observation.

OpenStax Chemistry 2e, 13.3 Shifting Equilibria: Le Châtelier’s Principle, exercise 18

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Adapted from General Chemistry © 2019 Rice University. Licensed under CC BY 4.0. Sources: Chemistry 2e, Chemistry: Atoms First 2e. Imported at revision 32c7196.