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12.4 Exercise 17

Avg difficulty 2.5

Nitroglycerine is an extremely sensitive explosive. In a series of carefully controlled experiments, samples of the explosive were heated to 160 °C and their first-order decomposition studied. Determine the average rate constants for each experiment using the following data:

Initial [C3H5N3O9] (M) 4.88 3.52 2.29 1.81 5.33 4.05 2.95 1.72
t (s) 300 300 300 300 180 180 180 180
% Decomposed 52.0 52.9 53.2 53.9 34.6 35.9 36.0 35.4

OpenStax Chemistry 2e, 12.4 Integrated Rate Laws, exercise 17

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Adapted from General Chemistry © 2019 Rice University. Licensed under CC BY 4.0. Sources: Chemistry 2e, Chemistry: Atoms First 2e. Imported at revision 32c7196.