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5.3 Exercise 21

Avg difficulty 2.5

The following sequence of reactions occurs in the commercial production of aqueous nitric acid:
4NH3(g)+5O2(g)⟶4NO(g)+6H2O(l)ΔH=−907kJ4 \text{NH}_{3} \left(g\right) + 5 \text{O}_{2} \left(g\right) \rightarrow 4 \text{NO} \left(g\right) + 6 \text{H}_{2} \text{O} \left(l\right) \Delta \text{H} = −907 \text{kJ}
2NO(g)+O2(g)⟶2NO2(g)ΔH=−113kJ2 \text{NO} \left(g\right) + \text{O}_{2} \left(g\right) \rightarrow 2 \text{NO}_{2} \left(g\right) \Delta \text{H} = −113 \text{kJ}
3NO2+H2O(l)⟶2HNO3(aq)+NO(g)ΔH=−139kJ3 \text{NO}_{2} + \text{H}_{2} \text{O} \left(l\right) \rightarrow 2 \text{HNO}_{3} \left(a q\right) + \text{NO} \left(g\right) \Delta \text{H} = −139 \text{kJ}

Determine the total enthalpy change for the production of one mole of aqueous nitric acid by this process. Coproducts of the net reaction include water and nitrogen monoxide.

OpenStax Chemistry 2e, 5.3 Enthalpy, exercise 21

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Adapted from General Chemistry © 2019 Rice University. Licensed under CC BY 4.0. Sources: Chemistry 2e, Chemistry: Atoms First 2e. Imported at revision 32c7196.