Back to 16.3 The Second and Third Laws of Thermodynamics

16.3 Exercise 10

Avg difficulty 2.5

Use the standard entropy data in Appendix G to determine the change in entropy for each of the following reactions. All the processes occur at the standard conditions and 25 °C.

(a) C(s, graphite)+O2(g)⟶CO2(g)\text{C} \left(s ,\text{ graphite}\right) + \text{O}_{2} \left(g\right) \rightarrow \text{CO}_{2} \left(g\right)

(b) O2(g)+N2(g)⟶2NO(g)\text{O}_{2} \left(g\right) + \text{N}_{2} \left(g\right) \rightarrow \text{2NO} \left(g\right)

(c) 2Cu(s)+S(g)⟶Cu2S(s)\text{2Cu} \left(s\right) + \text{S} \left(g\right) \rightarrow \text{Cu}_{2} \text{S} \left(s\right)

(d) CaO(s)+H2O(l)⟶Ca(OH)2(s)\text{CaO} \left(s\right) + \text{H}_{2} \text{O} \left(l\right) \rightarrow \text{Ca} \left(\text{OH}\right)_{2} \left(s\right)

(e) Fe2O3(s)+3CO(g)⟶2Fe(s)+3CO2(g)\text{Fe}_{2} \text{O}_{3} \left(s\right) + \text{3CO} \left(g\right) \rightarrow \text{2Fe} \left(s\right) + \text{3CO}_{2} \left(g\right)

(f) CaSO4·2H2O(s)⟶CaSO4(s)+2H2O(g)\text{CaSO}_{4} \cdot \text{2H}_{2} \text{O} \left(s\right) \rightarrow \text{CaSO}_{4} \left(s\right) + \text{2H}_{2} \text{O} \left(g\right)

OpenStax Chemistry 2e, 16.3 The Second and Third Laws of Thermodynamics, exercise 10

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Adapted from General Chemistry © 2019 Rice University. Licensed under CC BY 4.0. Sources: Chemistry 2e, Chemistry: Atoms First 2e. Imported at revision 32c7196.