Back to 16.3 The Second and Third Laws of Thermodynamics

16.3 Exercise 8

Avg difficulty 2.5

By calculating ΔSuniv at each temperature, determine if the melting of 1 mole of NaCl(s) is spontaneous at 500 °C and at 700 °C.
SNaCl(s)°=72.11Jmol·KSNaCl(l)°=95.06Jmol·KΔHfusion°=27.95 kJ/molS_{\text{NaCl} \left(s\right)}^{\circ} = 72.11 \frac{\text{J}}{\text{mol}\cdot\text{K}} S_{\text{NaCl} \left(l\right)}^{\circ} = 95.06 \frac{\text{J}}{\text{mol}\cdot\text{K}} \Delta H_{\text{fusion}}^{\circ} = \text{27}.\text{95 kJ}/\text{mol}

What assumptions are made about the thermodynamic information (entropy and enthalpy values) used to solve this problem?

OpenStax Chemistry 2e, 16.3 The Second and Third Laws of Thermodynamics, exercise 8

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Adapted from General Chemistry © 2019 Rice University. Licensed under CC BY 4.0. Sources: Chemistry 2e, Chemistry: Atoms First 2e. Imported at revision 32c7196.