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4.4 Reaction Yields

Finding which reactant runs out first, computing the theoretical yield it permits, and comparing an actual yield against it as a percentage.

Chemistry 2e, 4.4 Reaction Yields

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8 exercises

4.4 Exercise 2

What is the limiting reactant in a reaction that produces sodium chloride from 8 g of sodium and 8 g of diatomic chlorine?

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4.4 Exercise 4

A student isolated 25 g of a compound following a procedure that would theoretically yield 81 g. What was his percent yield?

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4.4 Exercise 6

Freon-12, CCl2F2, is prepared from CCl4 by reaction with HF. The other product of this reaction is HCl. Outline the steps needed to determine the percent yield of a reaction that produces 12.5 g of CCl2F2 from 32.9 g of CCl4. Freon-12 has been banned and is no longer used as a refrigerant because it catalyzes the decomposition of ozone and has a very long lifetime in the atmosphere. Determine the…

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4.4 Exercise 8

Toluene, C6H5CH3, is oxidized by air under carefully controlled conditions to benzoic acid, C6H5CO2H, which is used to prepare the food preservative sodium benzoate, C6H5CO2Na. What is the percent yield of a reaction that converts 1.000 kg of toluene to 1.21 kg of benzoic acid?

2C6H5CH3+3O2⟶2C6H5CO2H+2H2O2 \text{C}_{6} \text{H}_{5} \text{CH}_{3} + 3 \text{O}_{2} \rightarrow 2 \text{C}_{6} \text{H}_{5} \text{CO}_{2} \text{H} + 2 \text{H}_{2} \text{O}

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4.4 Exercise 10

Outline the steps needed to solve the following problem, then do the calculations. Ether, (C2H5)2O, which was originally used as an anesthetic but has been replaced by safer and more effective medications, is prepared by the reaction of ethanol with sulfuric acid.

2C2H5OH + H2SO4 ⟶ (C2H5)2O + H2SO4·H2O

What is the percent yield of ether if 1.17 L (d = 0.7134 g/mL) is isolated from the reaction of 1…

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4.4 Exercise 12

Outline the steps needed to determine the limiting reactant when 0.50 mol of Cr and 0.75 mol of H3PO4 react according to the following chemical equation.
2Cr+2H3PO4⟶2CrPO4+3H22 \text{Cr} + 2 \text{H}_{3} \text{PO}_{4} \rightarrow 2 \text{CrPO}_{4} + 3 \text{H}_{2}

Determine the limiting reactant.

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4.4 Exercise 14

Uranium can be isolated from its ores by dissolving it as UO2(NO3)2, then separating it as solid UO2(C2O4)·3H2O. Addition of 0.4031 g of sodium oxalate, Na2C2O4, to a solution containing 1.481 g of uranyl nitrate, UO2(NO3)2, yields 1.073 g of solid UO2(C2O4)·3H2O.

Na2C2O4 + UO2(NO3)2 + 3H2O ⟶ UO2(C2O4)·3H2O + 2NaNO3

Determine the limiting reactant and the percent yield of this reaction.

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4.4 Exercise 18

Would you agree to buy 1 trillion (1,000,000,000,000) gold atoms for $5? Explain why or why not. Find the current price of gold at http://money.cnn.com/data/commodities/ (1 troy ounce=31.1 g)\left(\text{1 troy ounce} = \text{31}.\text{1 g}\right)

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Adapted from General Chemistry © 2019 Rice University. Licensed under CC BY 4.0. Sources: Chemistry 2e, Chemistry: Atoms First 2e. Imported at revision 32c7196.